Bonded Phases — Contents

Table of Contents

Introduction to Bonded Phases
Charactersitics of Bonded Phases
The Different Classes of Bonded Phase
BrushType Bonded Phases
OligomericType Bonded Phases
Bulk Type Bonded Phases
The Synthesis of Bonded Phases
Bonded Phase Synthesis by Reaction in a Solvent
The Carbon Content of Bonded Phases
The Use of Alkoxysilane Reagents in Bonded Phase Synthesis
The Large Scale Preparation of Bonded Phases
The Fluidized Bed Method for Bonded Phase Synthesis
The Preparation of an Oligomeric Bonded Phase
Synthesis of Bonded Phases by Surface Cross-Linking
Choosing a Bonded Phase
The Characteristics of Reverse Phases
Molecular Forces
Van der Waals radii
Ionic Interactions
Polar Interactions
Dispersive Interactions
The Retention Properties of Bulk and Brush Phases
The Wetting Characteristics of Brush and Bulk Reverse Phases
The Oligomeric Phases
The Stability of Oligomeric Phases
The Retention Properties of Oligomeric Phases
Solvent Solute Interactions with the Surface of a Reverse Phase
Solvent Interactions with the Surface
The Derivation of the Langmuir Adsorption Isotherm for Reverse Phases
Application of the Theory to the Adsorption of Aliphatic Alcohols
Application of the Theory to the Adsorption of Aliphatic Acids
The Relationship between (K) and the Carbon Number of a Solvent/Solute
The Adsorption of Ion Exchange Reagents on the Surface of Reverse Phases
Solute Interaction with the Reverse Phase Surface
References