The Thermodynamics of Chromatography - The Distribution of Standard Energy Between Different Types of Molecular Interactions > The Concept of Complex Formation > Page 52

 

They are as follows,

where () is the specific retention volume of a noncomplexing solute with a vapor pressure () and a noncomplexing stationary phase having a molecular weight ();

where () is the specific retention volume of the same noncomplexing solute with a pure complexing stationary phase having a molecular weight ();