The Thermodynamics of Chromatography - The Distribution of Standard Energy Between Different Types of Molecular Interactions > The Concept of Complex Formation > Page 50
At infinite
dilution, () and (
) will tend to unity, (
)
and (
) will tend to zero and (
)
and (
) will tend to (
) and (
)
respectively.
Thus,
Defining a new constant
(K'), where ,