Dispersion in Chromatography Columns - Experimental Validation of the Van Deemter Equation > Page 96

J.Chromatogr.,270(1983)47.

Figure 27

f(1) = and f(2)=

Figure 27. Graph of  against  for both (k') and (k'e)

It follows, that the excluded dead volume must not only be used for measuring mobile phase velocities in kinetic studies of LC columns and also for LC column design but it must also be employed for the measurement of capacity factors.