The Thermodynamics of Chromatography - Interactions Between the Atoms of Hydrogen, Carbon, Chlorine and Bromine and an Exclusively Dispersive Stationary Phase > Page 30

 

                               (20)

 

 

and for the chlorine substituted monobromomethanes,

 

            (21)

and for the bromine substituted monochloromethanes will be,

    log(K) =  DG'C  + DG'Cl   + (3-n)DG'H + nDG'Br)